DocumentCode :
3164961
Title :
Phenol degradation property of Fe-based amorphous alloys with different composition
Author :
Yimin Sun ; Pan Wang ; Xiufang Bian
Author_Institution :
Sch. of Mater. Sci. & Eng., Shandong Univ., Jinan, China
Volume :
2
fYear :
2014
fDate :
19-21 Aug. 2014
Firstpage :
621
Lastpage :
625
Abstract :
The catalytic degradation properties of Fe-based amorphous alloys with different compositions on phenol contaminants were studied, and the results showed that the Fe78Si9B13 possesses superior catalytic activity than the Fe73.5Nb3Cu1Si13.5B9. Samples annealed at temperature of 100°C for 24h were proved to have higher catalytic degradation rate than the original ones. Kinetics analysis based on the experimental dates elucidated that the phenol degradation process can be described by the first-order kinetic model. Structural analysis through XRD, DSC and SEM demonstrated that there is a closed relationship between the catalytic activities of the Fe-based amorphous and the amorphous structure. The types of element conThe catalytic degradation properties of Fe-based amorphous alloys with different compositions on phenol contaminants were studied, and the results showed that the Fe78Si9B13 possesses superior catalytic activity than the Fe73.5Nb3Cu1Si13.5B9. Samples annealed at temperature of 100°C for 24h were proved to have higher catalytic degradation rate than the original ones. Kinetics analysis based on the experimental dates elucidated that the phenol degradation process can be described by the first-order kinetic model. Structural analysis through XRD, DSC and SEM demonstrated that there is a closed relationship between the catalytic activities of the Fe-based amorphous and the amorphous structure. The types of element contained in the Fe-based amorphous alloys have great effect on their catalytic activity.tained in the Fe-based amorphous alloys have great effect on their catalytic activity.
Keywords :
catalysis; catalysts; iron alloys; metallurgy; reaction kinetics; water pollution; DSC; Fe-based amorphous alloys; Fe78Si9B13; SEM; XRD; catalytic activity; catalytic degradation properties; first-order kinetic model; kinetics analysis; phenol contaminants; phenol degradation property; structural analysis; Degradation; Iron; Niobium; Oxidation; Passivation; Water pollution; Fe-based amorphous alloys; heterogeneous Fenton reaction; phenol degradation;
fLanguage :
English
Publisher :
ieee
Conference_Titel :
Materials for Renewable Energy and Environment (ICMREE), 2013 International Conference on
Conference_Location :
Chengdu
Print_ISBN :
978-1-4799-3335-8
Type :
conf
DOI :
10.1109/ICMREE.2013.6893750
Filename :
6893750
Link To Document :
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