• DocumentCode
    3439736
  • Title

    Study of microstructure and defects in hydrogenated microcrystalline silicon films

  • Author

    Peng, Wenbo ; Zeng, Xiangbo ; Liu, Shiyong ; Xiao, Haibo ; Kong, Guanglin ; Yu, Yude ; Liao, Xianbo

  • Author_Institution
    Key Lab. of Semicond. Mater. Sci., Chinese Acad. of Sci., Beijing, China
  • fYear
    2009
  • fDate
    7-12 June 2009
  • Abstract
    Microcrystalline silicon films were deposited by very high frequency (VHF) plasma-enhanced chemical vapor deposition (PECVD) with different hydrogen dilution. The microstructure of these films was investigated using Raman spectroscopy and infrared absorption (IR) spectra. The crystalline, amorphous, and grain boundary volume fractions Xc, Xa and Xgb were estimated from Raman measurements. An interface structure factor (Rif) is proposed to characterize the grain boundary volume fractions in IR spectroscopy. The density of states (DOS) of the microcrystalline crystalline silicon films were studied by phase-shift analysis of modulated photocurrent (MPC) and photoconductivity spectroscopy. It was observed that DOS increases with increasing grain boundary volume fractions, while the values of electron mobility-lifetime product ¿eTe decease.
  • Keywords
    Raman spectra; carrier lifetime; electron mobility; elemental semiconductors; grain boundaries; hydrogen; infrared spectra; interface structure; photoconductivity; semiconductor thin films; silicon; IR spectroscopy; Raman spectroscopy; Si:H; density of states; electron mobility-lifetime product; grain boundary; hydrogenated microcrystalline silicon films; infrared absorption spectra; interface structure factor; microstructure; modulated photocurrent; phase-shift analysis; photoconductivity spectroscopy; plasma-enhanced chemical vapor deposition; volume fractions; Crystallization; Frequency; Grain boundaries; Infrared spectra; Microstructure; Photoconductivity; Plasma chemistry; Semiconductor films; Silicon; Spectroscopy;
  • fLanguage
    English
  • Publisher
    ieee
  • Conference_Titel
    Photovoltaic Specialists Conference (PVSC), 2009 34th IEEE
  • Conference_Location
    Philadelphia, PA
  • ISSN
    0160-8371
  • Print_ISBN
    978-1-4244-2949-3
  • Electronic_ISBN
    0160-8371
  • Type

    conf

  • DOI
    10.1109/PVSC.2009.5411197
  • Filename
    5411197