Title :
Integration of high sheet resistance homogeneous emitters in a process flow for PERC-type solar cells with Cu contacts
Author :
Ngamo, M. ; Tous, Loic ; Cornagliotti, Emanuele ; Horzel, J. ; Janssens, T. ; Russell, R. ; Poortmans, Jozef ; Lombardet, B.
Author_Institution :
TOTAL Gas & Power, Paris la défense, France
Abstract :
This paper presents the results of the integration of a high sheet resistance (120 Ω/sq) homogeneous emitter with an industrial feasible process flow on large area p-type CZ-Si PERC solar cells with plated Ni-Si/Cu front contacts. Focus is put on the junction isolation performed by either applying a mask prior to POCl3 diffusion or by selectively removing the rear side emitter in an inline 1-sided wet-chemical etching tool after diffusion. A metallization sequence [1,2] applying Ni and Cu plating, is performed to contact the moderately doped emitters. The best experimental split in this comparison resulted in excellent average conversion efficiency of 20.2%.
Keywords :
copper; etching; oxygen compounds; phosphorus compounds; semiconductor device metallisation; silicon; solar cells; Cu; POCl3; Si; conversion efficiency; diffusion; high sheet resistance homogeneous emitter integration; industrial feasible process flow; inline 1-sided wet-chemical etching tool; large area p-type CZ-Si PERC-type solar cells; metallization sequence; Dielectrics; Impurities; Oxidation; Photovoltaic cells; Resistance; Silicon; Surface treatment; 120 ohm/sq emitter; Cu plating; PERC-type solar cells; emitter removal;
Conference_Titel :
Photovoltaic Specialists Conference (PVSC), 2012 38th IEEE
Conference_Location :
Austin, TX
Print_ISBN :
978-1-4673-0064-3
DOI :
10.1109/PVSC.2012.6318294