Title :
Resonance Raman spectroscopy of the 2-chloro-allyl radical
Author :
Kelly, P.B. ; Xianmung Liu ; Getty, James D
Author_Institution :
Dept. of Chem., California Univ., Davis, CA, USA
Abstract :
Summary form only given. Resonance Raman spectroscopy has been employed to examine the substitution effects on the allyl radical. The 2-chloroallyl radical (CH/sub 2/CClCH/sub 2/) is detected with excitation from 220 nm to 245 nm. The Raman spectra can be analyzed to obtain information regarding both the ground state vibrational structure and the excited slate dynamics of the radical.
Keywords :
Raman spectra; excited states; free radicals; infrared spectra; organic compounds; vibrational states; 2-chloro-allyl radical; 2-chloroallyl radical; 220 to 245 nm; CH/sub 2/CClCH/sub 2/; IR spectra; Raman spectra; allyl radical; excited slate dynamics; ground state vibrational structure; resonance Raman spectroscopy; substitution effects; Bonding; Equations; Frequency; Gases; Geometry; Laser modes; Pump lasers; Raman scattering; Resonance; Spectroscopy;
Conference_Titel :
Quantum Electronics and Laser Science Conference, 1996. QELS '96., Summaries of Papers Presented at the
Conference_Location :
Anaheim, CA, USA
Print_ISBN :
1-55752-444-0
