Title :
InGaAs/GaAs QD superlattices: MOVPE growth, structural and optical characterization, and application in intermediate-band solar cells
Author :
Norman, A.G. ; Hanna, M.C. ; Dippo, P. ; Levi, D.H. ; Reedy, R.C. ; Ward, J.S. ; Al-Jassim, M.M.
Author_Institution :
Nat. Renewable Energy Lab., Golden, CO, USA
Abstract :
We report on the growth and characterization of InGaAs/GaAs quantum dot (QD) superlattices for application in intermediate-band solar cells (IBSCs). Good optical and structural quality QD superlattices with up to 50 periods were obtained by metal-organic vapor-phase epitaxy (MOVPE) growth on {113}B GaAs substrates. Solar cells containing Si ∂-doped and undoped QD superlattice absorption regions have been fabricated and their performance compared with control cells containing undoped GaAs or undoped InGaAs/GaAs superlattice absorption regions. The QD superlattice cells exhibited photoresponses extended to longer wavelengths than the control cells. The introduction of QDs to the absorbing region of the solar cells resulted in a decrease in the open-circuit voltages and, in some cases, a decrease in the short-circuit currents of the cells.
Keywords :
III-V semiconductors; MOCVD; band structure; elemental semiconductors; gallium arsenide; indium compounds; semiconductor doping; semiconductor growth; semiconductor quantum dots; semiconductor superlattices; short-circuit currents; silicon; solar cells; vapour phase epitaxial growth; GaAs; GaAs substrates; InGaAs-GaAs:Si; InGaAs/GaAs quantum dot superlattices; MOVPE growth; Si ∂-doped QD superlattice absorption regions; control cells; intermediate-band solar cells; metal-organic vapor-phase epitaxial growth; open-circuit voltages; optical characterization; photoresponse; short-circuit current; structural characterization; undoped GaAs superlattice absorption regions; undoped InGaAs/GaAs superlattice absorption regions; undoped QD superlattice absorption regions; Absorption; Epitaxial growth; Epitaxial layers; Gallium arsenide; Indium gallium arsenide; Metallic superlattices; Optical superlattices; Photovoltaic cells; Quantum dots; Substrates;
Conference_Titel :
Photovoltaic Specialists Conference, 2005. Conference Record of the Thirty-first IEEE
Print_ISBN :
0-7803-8707-4
DOI :
10.1109/PVSC.2005.1488065