DocumentCode
445707
Title
Studies toward the enantioselective total synthesis of 3/spl alpha/-hydroxy-15-rippertene
Author
Kreuzer, Thomas ; Metz, Peter
Author_Institution
Dresden Univ. of Technol.
Volume
2
fYear
2004
fDate
June 26 2004-July 3 2004
Firstpage
51
Abstract
The tetracyclic diterpene 3alpha-hydroxy-15-rippertene (1) was isolated from the defensive secretion of the higher termites Nasutitermes rippertii and Nasutitermes ephratae by Prestwich et al. Herein we report the synthesis of two advanced hydroazulene key intermediates for the enantioselective total synthesis of 1
Keywords
catalysis; chemical exchanges; isomerisation; materials preparation; organic compounds; oxidation; 3alpha-hydroxy-15-rippertene; Lewis acid-catalyzed ring expansion; Nasutitermes ephratae; Nasutitermes rippertii; copper induced allylic substitution; defensive secretion; enantiomeric isolation; enantioselective total synthesis; hydroazulene key intermediates; oxidation; termites; tetracyclic diterpene; Chemical technology; Chemistry; Civil engineering; Copper; Fluids and secretions; Isolation technology; Oxidation; Platinum; Silicon; Skeleton;
fLanguage
English
Publisher
ieee
Conference_Titel
Science and Technology, 2004. KORUS 2004. Proceedings. The 8th Russian-Korean International Symposium on
Conference_Location
Tomsk
Print_ISBN
0-7803-8383-4
Type
conf
DOI
10.1109/KORUS.2004.1555536
Filename
1555536
Link To Document