In-Situ $I\hbox {--}V$ Measurements of ${\rm ZnS}{:}{\rm TiO}_{2}/{\rm p}\hbox {-}{\rm Si}$

The 120 MeV Au⁹⁺ ion induced modifications in a ZnS:TiO₂/p-Si quantum dot (QD) heterojunction has been studied by In-Situ current-voltage (I-V) measurements. This paper shows that the process of ion irradiation is a novel technique in modifying the electronic properties of QDs based semiconductor heterojunctions. After Au⁹⁺ ion irradiation, there is an increase in ideality factor for ZnS:TiO₂/p-Si QDs heterojunction at lower fluences and further at higher fluences the ideality factor decreases. In addition, the other parameters like leakage current, series resistance, and reverse saturation current are also affected under the SHI irradiation. In pristine samples, the dependence of the currents under the light illumination shows high photo responsivity. The observed responsivity is 2.7×10¹⁰ A/W for ultraviolet light (wavelength 376 nm) at reverse bias voltage 1.5 V. The increase in responsivity to 4.9×10¹⁰ A/W is observed after irradiation up to fluence of 3×10¹³ ions/cm².