• DocumentCode
    65277
  • Title

    Dielectric Barrier Discharge Assisted Transformation of Cyclohexane to \\hbox {C}_{1} and \\hbox {C}_{2</h1></div></div> </li> <li class='list-group-item border-0 py-3 px-0'> <div class='row g-0 align-items-center mb-2'><div class='col-12 col-md-3 fullRecLabelEnglish fw-bold mb-2 mb-md-0'><span class='text-muted small'>Author</span></div><div class='col-12 col-md-9 leftDirection leftAlign'><h2 class='mb-0 fw-semibold'>Dey, G.R. ; Das, T.N.</h2></div></div> </li> <li class='list-group-item border-0 py-3 px-0'> <div class='row g-0 align-items-center mb-2'><div class='col-12 col-md-3 fullRecLabelEnglish fw-bold mb-2 mb-md-0'><span class='text-muted small'>Author_Institution</span></div><div class='col-12 col-md-9 leftDirection leftAlign'>Radiat. & Photochem. Div., Bhabha Atomic Res. Centre, Mumbai, India</div></div> </li> <li class='list-group-item border-0 py-3 px-0'> <div class='row g-0 align-items-center mb-2'><div class='col-12 col-md-3 fullRecLabelEnglish fw-bold mb-2 mb-md-0'><span class='text-muted small'>Volume</span></div><div class='col-12 col-md-9 leftDirection leftAlign'>41</div></div> </li> <li class='list-group-item border-0 py-3 px-0'> <div class='row g-0 align-items-center mb-2'><div class='col-12 col-md-3 fullRecLabelEnglish fw-bold mb-2 mb-md-0'><span class='text-muted small'>Issue</span></div><div class='col-12 col-md-9 leftDirection leftAlign'>1</div></div> </li> <li class='list-group-item border-0 py-3 px-0'> <div class='row g-0 align-items-center mb-2'><div class='col-12 col-md-3 fullRecLabelEnglish fw-bold mb-2 mb-md-0'><span class='text-muted small'>fYear</span></div><div class='col-12 col-md-9 leftDirection leftAlign'>2013</div></div> </li> <li class='list-group-item border-0 py-3 px-0'> <div class='row g-0 align-items-center mb-2'><div class='col-12 col-md-3 fullRecLabelEnglish fw-bold mb-2 mb-md-0'><span class='text-muted small'>fDate</span></div><div class='col-12 col-md-9 leftDirection leftAlign'>Jan. 2013</div></div> </li> <li class='list-group-item border-0 py-3 px-0'> <div class='row g-0 align-items-center mb-2'><div class='col-12 col-md-3 fullRecLabelEnglish fw-bold mb-2 mb-md-0'><span class='text-muted small'>Firstpage</span></div><div class='col-12 col-md-9 leftDirection leftAlign'>140</div></div> </li> <li class='list-group-item border-0 py-3 px-0'> <div class='row g-0 align-items-center mb-2'><div class='col-12 col-md-3 fullRecLabelEnglish fw-bold mb-2 mb-md-0'><span class='text-muted small'>Lastpage</span></div><div class='col-12 col-md-9 leftDirection leftAlign'>146</div></div> </li> <li class='list-group-item border-0 py-3 px-0'> <div class='row g-0 align-items-center mb-2'><div class='col-12 col-md-3 fullRecLabelEnglish fw-bold mb-2 mb-md-0'><span class='text-muted small'>Abstract</span></div><div class='col-12 col-md-9 leftDirection leftAlign'>Efficient transformation of cyclohexane<i>g</i> to methane, ethylene, and acetylene in argon dielectric barrier discharge is reported. In the absence of another H-atom donating source in the reaction mixture, such products´ generation suggests in situ fragmentation of a fraction of parent molecules to C<sub>1</sub> and C<sub>2</sub> stages, followed by preferential reactions of these fragments with H-atoms freed along. Simultaneous formation of nonvolatile deposits containing diverse oxygenated and nonoxygenated long-chained aliphatic and cyclic compounds also occurred due to the remaining fraction´s reactions, including some with the unreacted parent and the adsorbed moisture on dielectric surfaces. The presence of 4% O<sub>2</sub> in the gas mixture induced a significant decrease in gas-phase hydrocarbons´ yields in addition to a change in the nonvolatile products´ nature.</div></div> </li> <li class='list-group-item border-0 py-3 px-0'> <div class='row g-0 align-items-center mb-2'><div class='col-12 col-md-3 fullRecLabelEnglish fw-bold mb-2 mb-md-0'><span class='text-muted small'>Keywords</span></div><div class='col-12 col-md-9 leftDirection leftAlign'>discharges (electric); free radical reactions; organic compounds; plasma chemistry; plasma sources; C1 hydrocarbons; C2 hydrocarbons; DBD assisted cyclohexane transformation; H-atom donating source; acetylene; aliphatic compounds; argon DBD; cyclic compounds; dielectric barrier discharge; ethylene; in situ fragmentation; methane; nonoxygenated long chained compounds; nonvolatile deposits; oxygenated long chained compounds; parent molecules; preferential reactions; reaction mixture; Argon; Degradation; Dielectrics; Discharges (electric); Frequency measurement; Hydrocarbons; Surface treatment; <formula formulatype=$hbox{C}_{1}{-}hbox{C}_{2}$ hydrocarbons; Cyclohexane; dielectric barrier discharge (DBD); free-radical reactions; gas chromatograph;

  • fLanguage
    English
  • Journal_Title
    Plasma Science, IEEE Transactions on
  • Publisher
    ieee
  • ISSN
    0093-3813
  • Type

    jour

  • DOI
    10.1109/TPS.2012.2220571
  • Filename
    6342921
    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=49&DC=65277