Title :
Catalytic upgrading of wood-plastic composite fast pyrolysis vapors with USY/ HUSY catalysts
Author :
Jian-ping Sun ; Shu-juan Sui ; Zhi-jun Zhang ; Shun Tan ; Qing-wen Wang
Author_Institution :
Key Lab. of Bio-Based Mater. Sci. & Technol. of Minist. of Educ, Northeast Forestry Univ., Harbin, China
Abstract :
Ultra stable Y type(USY) zeolite and HUSY zeolite were applied to catalytic cracking of wood-plastic composite(WPC) fast pyrolysis vapors using analytical pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS). Compared with the results of non-catalytic pyrolysis, there was a dramatic increase in the concentration of olefins and aromatic compounds of the derived pyrolytic products. The catalysts significantly reduced aldehydes, acetic acid and ketones. In addition, levoglucosan was completely eliminated after catalysis. The results showed that both USY and HUSY zeolite exhibited high activity in the decarboxylation and decarbonylation of the pyrolytic products, and USY performed better than HUSY.
Keywords :
chromatography; composite materials; pyrolysis; wood; zeolites; Py-GC/MS; USY/ HUSY zeolite catalysts; analytical pyrolysis-gas chromatography-mass spectrometry; catalytic cracking; decarbonylation; decarboxylation; fast pyrolysis; ultra stable Y type zeolite; wood plastic composite; Biomass; Compounds; Heating; Hydrocarbons; Plastics; Wool; Py-GC/MS; USY/ HUSY; Wood-Plastic Composite; catalytic cracking; fast pyrolysis;
Conference_Titel :
Materials for Renewable Energy and Environment (ICMREE), 2013 International Conference on
Conference_Location :
Chengdu
Print_ISBN :
978-1-4799-3335-8
DOI :
10.1109/ICMREE.2013.6893660