Pulsed Discharge Irradiance Reaction Identification

This paper presents the application of a theoretically developed method, which when applied to a pulsed irradiance signal can provide information about the underlying chemical kinetics and reaction dynamics. The theoretical development uses a combination of state-space, Laplace transform, least-square, and correlation techniques to determine chemical kinetic and reaction dynamic terms from a pulsed discharge. The waveform irradiance signals come from a space-based optical radiometer. Four pulsed radiometry irradiance waveforms are examined where the reaction order, rate constant, and reaction rates are investigated. The application of the theory and the commensurate results demonstrate that irradiance signals obtained under similar circumstances come from distinct pulsed discharge conditions.